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oxabicyclic alkenes, isoquinoline, regioselectivity, ring-opening, rhodium catalysis (1)
Oxazolidinone polycyclitol, Oxazolidinone, Aminocarbasugar, Aminocyclitol (1)
PERIPHERAL ANIONIC SITE; STEREOSPECIFIC SYNTHESIS; ANTIOXIDANT; ACETYLCHOLINESTERASE; STRATEGY; DERIVATIVES; INHIBITORS; DISCOVERY; ORAC; MONO (1)
REDUCTIONS (1)
RING-CLOSING METATHESIS; (+)-PERICOSINE B; CHEMOENZYMATIC SYNTHESIS; MONOSUBSTITUTED BENZENES; SECONDARY METABOLITES; GENERAL PROCEDURE; CARBA-SUGARS; GABOSINE-G; DERIVATIVES; STREPTOMYCES (1)
SOLID-PHASE SYNTHESIS, STEREOSPECIFIC SYNTHESIS, INHIBITORS, CARBAMATE, DERIVATIVES, CAPRAVIRINE, DESIGN, ACCESS, HIV-1 (1)
Stereoselective synthesis of tricyclo[6.2.2.0(2,7)]dodecane-3,6,9,10-tetrol was developed starting from p-benzoquinone. The endo selective Diels-Alder cycloaddition of p-benzoquinone and 1,3-cyclohexadiene afforded the corresponding bicyclic diketone. The synthesis of the title compound was based on the cycloadduct by selective reduction with NaBH4, acetylation with AcCl, and hydroxylation with OsO4-NMO. [Supplementary materials are available for this article. Go to the publisher's online edition of Synthetic Communications (R) for the following free supplemental resource: Full experimental and spectral details.] (1)
STEREOSPECIFIC SYNTHESIS, MOLECULAR COMPLEXITY, INOSITOL, CARBASUGARS, INHIBITION, GENERATION, ANALOG (1)
STEREOSPECIFIC SYNTHESIS; EPOXIDES; BROMOCONDURITOL; METABOLITES (1)
STEREOSPECIFIC SYNTHESIS; MUSHROOM TYROSINASE; CONDURITOL; DERIVATIVES; STRATEGY; GLYCOSYLATION; GLUCOSIDASE; INHIBITORS; GLYCOSIDES; HYDROLYSIS (1)
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