| dc.contributor.author |
Dusunceli, Serpil Demir |
|
| dc.contributor.author |
Sahan, Mehmet Hanifi |
|
| dc.contributor.author |
Kaloglu, Murat |
|
| dc.contributor.author |
Ustun, Elvan |
|
| dc.contributor.author |
Ozdemir, Ismail |
|
| dc.date.accessioned |
2024-03-15T11:24:36Z |
|
| dc.date.available |
2024-03-15T11:24:36Z |
|
| dc.date.issued |
2022 |
|
| dc.identifier.citation |
Düsünceli, SD., Sahan, MH., Kaloglu, M., Üstün, E., Özdemir, I. (2022). Applications of quinoxaline-bridged bis(benzimidazolium) salts as ligand sources for the palladium-catalyzed Suzuki and Heck cross-coupling reactions in an aqueous medium. J. Chin. Chem. Soc., 69(11), 1937-1953. https://doi.org/10.1002/jccs.202200304 |
en_US |
| dc.identifier.issn |
0009-4536 |
|
| dc.identifier.issn |
2192-6549 |
|
| dc.identifier.uri |
http://dx.doi.org/10.1002/jccs.202200304 |
|
| dc.identifier.uri |
https://www.webofscience.com/wos/woscc/full-record/WOS:000860112500001 |
|
| dc.identifier.uri |
http://earsiv.odu.edu.tr:8080/xmlui/handle/11489/4530 |
|
| dc.description |
WoS Categories: Chemistry, Multidisciplinary |
en_US |
| dc.description |
Web of Science Index: Science Citation Index Expanded (SCI-EXPANDED) |
en_US |
| dc.description |
Research Areas: Chemistry |
en_US |
| dc.description.abstract |
In the present work, quinoxaline-bridged bis(benzimidazolium) salts were prepared by the reaction of 2,3-bis(bromomethyl) quinoxaline and 1-substituted benzimidazole. The structures of the bis(benzimidazolium) salts were characterized by NMR, FT-IR, and elemental analysis techniques. Also, the photophysical properties of salts were investigated by UV-Vis absorption and fluorescence emission spectroscopy. Next, these quinoxaline bridged bis(benzimidazolium) salts were used as bidentate benzimidazol-2-ylidene ligand precursors in the palladium-catalyzed Suzuki-Miyaura and Mizoroki-Heck cross-couplings. These salts exhibited moderate-to-high activity in the palladium-catalyzed cross-coupling reactions. |
en_US |
| dc.description.sponsorship |
Inonu Universitesi [FYL-2020-2093] |
en_US |
| dc.language.iso |
eng |
en_US |
| dc.publisher |
WILEY-V C H VERLAG GMBH-WEINHEIM |
en_US |
| dc.relation.isversionof |
10.1002/jccs.202200304 |
en_US |
| dc.rights |
info:eu-repo/semantics/openAccess |
en_US |
| dc.subject |
bis(benzimidazolium) salt, Heck coupling, N-heterocyclic carbene, palladium, quinoxaline, Suzuki coupling |
en_US |
| dc.subject |
N-HETEROCYCLIC CARBENE, PALLADIUM/IMIDAZOLIUM SALT, ARYL BROMIDES, PRECURSORS SYNTHESIS, COMPLEXES SYNTHESIS, OLEFIN METATHESIS, KINETIC STABILITY, PHOSPHINE-LIGANDS, BOND FORMATION, BASIS-SETS |
en_US |
| dc.title |
Applications of quinoxaline-bridged bis(benzimidazolium) salts as ligand sources for the palladium-catalyzed Suzuki and Heck cross-coupling reactions in an aqueous medium |
en_US |
| dc.type |
article |
en_US |
| dc.relation.journal |
JOURNAL OF THE CHINESE CHEMICAL SOCIETY |
en_US |
| dc.contributor.department |
Ordu Üniversitesi |
en_US |
| dc.contributor.authorID |
0000-0002-0587-7261 |
en_US |
| dc.contributor.authorID |
0000-0002-2770-5532 |
en_US |
| dc.contributor.authorID |
0000-0001-6325-0216 |
en_US |
| dc.identifier.volume |
69 |
en_US |
| dc.identifier.issue |
11 |
en_US |
| dc.identifier.startpage |
1937 |
en_US |
| dc.identifier.endpage |
1953 |
en_US |