| dc.contributor.author |
Kelebekli, Latif |
|
| dc.contributor.author |
Celik, Murat |
|
| dc.contributor.author |
Kara, Yunus |
|
| dc.date.accessioned |
2024-03-15T11:23:59Z |
|
| dc.date.available |
2024-03-15T11:23:59Z |
|
| dc.date.issued |
2010 |
|
| dc.identifier.citation |
Kelebekli, L., Celik, M., Kara, Y. (2010). A novel and stereospecific synthesis of aminocyclitol: N-tosyldihydroconduramine E2. J. Chem. Res, 1, 54-56. https://doi.org/10.3184/030823410X12628681698796 |
en_US |
| dc.identifier.issn |
1747-5198 |
|
| dc.identifier.issn |
2047-6507 |
|
| dc.identifier.uri |
http://dx.doi.org/10.3184/030823410X12628681698796 |
|
| dc.identifier.uri |
https://www.webofscience.com/wos/woscc/full-record/WOS:000275412500016 |
|
| dc.identifier.uri |
http://earsiv.odu.edu.tr:8080/xmlui/handle/11489/4525 |
|
| dc.description |
WoS Categories: Chemistry, Multidisciplinary |
en_US |
| dc.description |
Web of Science Index: Science Citation Index Expanded (SCI-EXPANDED); Index Chemicus (IC); Current Chemical Reactions (CCR-EXPANDED) |
en_US |
| dc.description |
Research Areas: Chemistry |
en_US |
| dc.description.abstract |
A stereospecific synthesis of N-tosyldihydroconduramine E2, a new aminocyclitol, has been synthesised starting from cyclohexa-1,3-diene. The photooxygenation of cyclohexa-1,3-diene afforded the bicyclic endoperoxide. Reduction of the endoperoxide with thiourea and then reaction of the bis-carbamate with p-TsNCO followed by a palladium-catalysed ionisation/cyclisation reaction, gave a vinyl oxazolidin-2-one. Oxidation of the double bond in the oxazolidin-2-one with KMnO4 followed by acetylation, gave the oxazolidinone-diacetates. Hydrolysis of the oxazolidinone ring and removal of the acetate groups gave the desired aminocyclitol, N-tosyldihydroconduramine E2. |
en_US |
| dc.description.sponsorship |
TUBITAK (The Scientific and Technical Research Council of Turkey) [TBAG-105T162] |
en_US |
| dc.language.iso |
eng |
en_US |
| dc.publisher |
SAGE PUBLICATIONS LTD-LONDON |
en_US |
| dc.relation.isversionof |
10.3184/030823410X12628681698796 |
en_US |
| dc.rights |
info:eu-repo/semantics/openAccess |
en_US |
| dc.subject |
N-tosyldihydroconduramine E2, conduramine, aminocyclitol, endoperoxide |
en_US |
| dc.subject |
AMINOCYCLOPENTITOL GLYCOSIDASE INHIBITORS, ASYMMETRIC INDUCTION, RADICAL CYCLIZATION, CYCLITOLS, PURE |
en_US |
| dc.title |
A novel and stereospecific synthesis of aminocyclitol: N-tosyldihydroconduramine E2 |
en_US |
| dc.type |
article |
en_US |
| dc.relation.journal |
JOURNAL OF CHEMICAL RESEARCH |
en_US |
| dc.contributor.department |
Ordu Üniversitesi |
en_US |
| dc.identifier.issue |
1 |
en_US |
| dc.identifier.startpage |
54 |
en_US |
| dc.identifier.endpage |
56 |
en_US |