| dc.contributor.author |
Kelebekli, Latif |
|
| dc.date.accessioned |
2022-09-05T11:46:35Z |
|
| dc.date.available |
2022-09-05T11:46:35Z |
|
| dc.date.issued |
2013 |
|
| dc.identifier.uri |
http://doi.org/10.3184/174751913X13663103976700 |
|
| dc.identifier.uri |
http://earsiv.odu.edu.tr:8080/xmlui/handle/11489/3153 |
|
| dc.description.abstract |
2-Ethoxy-3- and 5-chloropyridines were obtained from 2,3- and 2,5-dichloropyridine. Reaction of 2,3- and 2,5-dichlo-ropyridines with tBuLi in the presence of furan gave 1- and 3-ethoxy-5,8-epoxy-5,8-dihydroisoquinolines. The rhodium-catalysed ring-opening reaction of 1- and 3-ethoxy-5,8-epoxy-5,8-dihydroisoquinolines with 2-bromophenol furnished the isomer 7-(2-bromophenoxy)-1-ethoxy-7,8-dihydroisoquinolin-8-ol, 6-(2-bromophenoxy)-1-ethoxy-5,6-dihydroisoquinolin-5-ol and 7-(2-bromophenoxy)-3-ethoxy-7,8-dihydroisoquinolin-8-ol, 6-(2-bromophenoxy)-3-ethoxy-5,6-dihydroisoquinolin-5-ol respectively. |
en_US |
| dc.language.iso |
eng |
en_US |
| dc.publisher |
SAGE PUBLICATIONS LTD1 OLIVERS YARD, 55 CITY ROAD, LONDON EC1Y 1SP, ENGLAND |
en_US |
| dc.relation.isversionof |
10.3184/174751913X13663103976700 |
en_US |
| dc.rights |
info:eu-repo/semantics/openAccess |
en_US |
| dc.subject |
oxabicyclic alkenes, isoquinoline, regioselectivity, ring-opening, rhodium catalysis |
en_US |
| dc.title |
Rhodium-catalysed nucleophilic ring opening reaction of 1-and 3-ethoxy-5,8-epoxy-5,8-dihydroisoquinolines |
en_US |
| dc.type |
article |
en_US |
| dc.relation.journal |
SAGE PUBLICATIONS LTD1 OLIVERS YARD, 55 CITY ROAD, LONDON EC1Y 1SP, ENGLAND |
en_US |
| dc.contributor.department |
Ordu Üniversitesi |
en_US |
| dc.contributor.authorID |
0000-0002-6242-2589 |
en_US |
| dc.identifier.volume |
5 |
en_US |
| dc.identifier.issue |
304 |
en_US |
| dc.identifier.startpage |
308 |
en_US |