| dc.contributor.author |
Dusunceli, S. Demir |
|
| dc.contributor.author |
Ozdemir, I. |
|
| dc.contributor.author |
Ustun, E. |
|
| dc.date.accessioned |
2022-08-17T06:46:48Z |
|
| dc.date.available |
2022-08-17T06:46:48Z |
|
| dc.date.issued |
2017 |
|
| dc.identifier.uri |
http://www.bcc.bas.bg/BCC_Volumes/Volume_49_Special_L_2017/BCC-49-L-2017.pdf |
|
| dc.identifier.uri |
https://www.researchgate.net/publication/320708575_MnCO3bpyN-2-chlorobenzylbenzimidazoleOTf_complex_as_a_new_photoactivatable_CO-releasing_molecule |
|
| dc.identifier.uri |
http://earsiv.odu.edu.tr:8080/xmlui/handle/11489/2572 |
|
| dc.description.abstract |
Metal carbonyl complexes have been accepted major for storage and transportation of carbon monoxide which is an important gasotransmitter. We synthesized novel manganese(I) carbonyl complex with general formula [Mn(CO)(3)(bpy)L] OTf (bpy = 2,2'-bipyridyl, L= N-(2-chlorobenzyl) benzimidazole, OTf = SO3CF3). The complex was characterized by LC-MS, H-1 NMR, 2D-COSY NMR, C-13 NMR, IR and elemental analysis. The CO-releasing properties of the complex were investigated. The DFT/TDDFT analyses were also made by ORCA package program. |
en_US |
| dc.language.iso |
eng |
en_US |
| dc.publisher |
BULGARIAN ACAD SCIENCE, CENTRAL LIBRARY 7 NOEMVRI NO 1, SOFIA, 00000, BULGARIA |
en_US |
| dc.rights |
info:eu-repo/semantics/openAccess |
en_US |
| dc.subject |
CORM; carbonyl complexes; manganese |
en_US |
| dc.subject |
GROUP-6 METAL-CARBONYLS; MANGANESE COMPLEXES; TRICARBONYL COMPLEXES; ANTIOXIDANT ACTIVITY; DFT CALCULATION; MONOXIDE; ELECTROCHEMISTRY; THERAPY; LIGANDS; DESIGN |
en_US |
| dc.title |
[Mn(CO)(3)(bpy)(N-2-chlorobenzylbenzimidazole)] OTf complex as a new photoactivatable CO-releasing molecule |
en_US |
| dc.type |
article |
en_US |
| dc.relation.journal |
BULGARIAN CHEMICAL COMMUNICATIONS |
en_US |
| dc.contributor.department |
Ordu Üniversitesi |
en_US |
| dc.contributor.authorID |
0000-0001-6325-0216 |
en_US |
| dc.contributor.authorID |
0000-0001-8765-4039 |
en_US |
| dc.contributor.authorID |
0000-0002-0587-7261 |
en_US |
| dc.identifier.volume |
49 |
en_US |
| dc.identifier.startpage |
50 |
en_US |
| dc.identifier.endpage |
56 |
en_US |