| dc.contributor.author |
Demir, Serpil |
|
| dc.contributor.author |
Koc, Sefika |
|
| dc.contributor.author |
Ozdemir, Ismail |
|
| dc.contributor.author |
Ustun, Elvan |
|
| dc.date.accessioned |
2022-08-17T06:42:14Z |
|
| dc.date.available |
2022-08-17T06:42:14Z |
|
| dc.date.issued |
2016 |
|
| dc.identifier.uri |
http://doi.org/10.1016/j.jorganchem.2016.05.001 |
|
| dc.identifier.uri |
https://www.sciencedirect.com/science/article/pii/S0022328X16301760?via%3Dihub |
|
| dc.identifier.uri |
http://earsiv.odu.edu.tr:8080/xmlui/handle/11489/2539 |
|
| dc.description.abstract |
Novel manganese(I) carbonyl complexes of the general formula [Mn(CO)(3)(bpy)L]PF6 (bpy = 2,2-bipyridyl, L = N-(2-methylbenzyl)imidazoline, N-(3-methylbenzyl)imidazoline, N-(4-methylbenzyl)imidazoline, N-(2,4,6-trimethylbenzyl)imidazoline) were synthesized and characterized by analytical (LC-MS spectrometry and elemental analysis) and spectroscopic (H-1 NMR, C-13 NMR, cosy2D-NMR, infrared) methods. The CO-releasing properties of these complexes were investigated with myoglobin assay. The DFT/TDDFT calculations were made by ORCA package program with both BP86 and B3LYP functionals. (C) 2016 Elsevier B.V. All rights reserved. |
en_US |
| dc.language.iso |
eng |
en_US |
| dc.publisher |
ELSEVIER SCIENCE SA, PO BOX 564, 1001 LAUSANNE, SWITZERLAND |
en_US |
| dc.relation.isversionof |
10.1016/j.jorganchem.2016.05.001 |
en_US |
| dc.rights |
info:eu-repo/semantics/openAccess |
en_US |
| dc.subject |
CO-releasing molecules; Photocorms; Imidazoline; Manganese; DFT/TDDFT; Metal carbonyl complexes |
en_US |
| dc.subject |
METAL-CARBONYLS; BASIS-SETS; CO-RMS; MOLECULES; LIGANDS; DERIVATIVES; STABILITY; TOXICITY; DESIGN; MO |
en_US |
| dc.title |
Carbon monoxide-releasing properties and DFT/TDDFT analysis of [Mn(CO)(3)(bpy)L]PF6 type novel manganese complexes |
en_US |
| dc.type |
article |
en_US |
| dc.relation.journal |
JOURNAL OF ORGANOMETALLIC CHEMISTRY |
en_US |
| dc.contributor.department |
Ordu Üniversitesi |
en_US |
| dc.contributor.authorID |
0000-0001-6325-0216 |
en_US |
| dc.contributor.authorID |
0000-0001-8765-4039 |
en_US |
| dc.contributor.authorID |
0000-0002-0587-7261 |
en_US |
| dc.contributor.authorID |
0000-0002-0587-7261 |
en_US |
| dc.identifier.volume |
815-816 |
en_US |
| dc.identifier.startpage |
16 |
en_US |
| dc.identifier.endpage |
22 |
en_US |