Please use this identifier to cite or link to this item: http://earsiv.odu.edu.tr:8080/xmlui/handle/11489/4683
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dc.contributor.authorSavas, Bedrettin-
dc.contributor.authorCatiker, Efkan-
dc.contributor.authorOzturk, Temel-
dc.contributor.authorMeyvaci, Erguel-
dc.date.accessioned2024-03-15T12:17:15Z-
dc.date.available2024-03-15T12:17:15Z-
dc.date.issued2021-
dc.identifier.citationSavas, B., Çatiker, E., Öztürk, T., Meyvaci, E. (2021). Synthesis and characterization of poly(α-methyl β-alanine)-poly(ε-caprolactone) tri arm star polymer by hydrogen transfer polymerization, ring-opening polymerization and click chemistry. J. Polym. Res., 28(2). https://doi.org/10.1007/s10965-020-02367-zen_US
dc.identifier.issn1022-9760-
dc.identifier.issn1572-8935-
dc.identifier.urihttp://dx.doi.org/10.1007/s10965-020-02367-z-
dc.identifier.urihttps://www.webofscience.com/wos/woscc/full-record/WOS:000608256700006-
dc.identifier.urihttp://earsiv.odu.edu.tr:8080/xmlui/handle/11489/4683-
dc.descriptionWoS Categories: Polymer Scienceen_US
dc.descriptionWeb of Science Index: Science Citation Index Expanded (SCI-EXPANDED)en_US
dc.descriptionResearch Areas: Polymer Scienceen_US
dc.description.abstractSynthesis of poly(alpha -methyl beta -alanine)-poly(epsilon -caprolactone) [PmBA-(PCL)2] tri arm star polymer was accomplished by click chemistry. For this purpose, poly(alpha -methyl beta -alanine) (PmBA) was synthesized from methacrylamide by hydrogen transfer polymerization (HTP). Terminally dibromo PmBA (PmBA-2Br) was obtained by using the end-group modification method. Terminally diazido poly(alpha -methyl beta -alanine) [PmBA-2N(3)] was synthesized by the reaction of PmBA-2Br and sodium azide. Terminally propargyl poly(epsilon -caprolactone) [PCL-propargyl] was obtained using epsilon -caprolactone and propargyl alcohol by ring-opening polymerization. By the reaction of PCL-propargyl and PmBA-2N(3), PmBA-(PCL)2 tri arm star polymer was synthesized via click chemistry. The characterizations of products were performed by using multi instruments including H-1-NMR, FT-IR, MALDI-MS, GPC, and SEM. Degradation features of the tri arm star polymer was investigated by using TGA technique. Water uptake measurement of the tri arm star polymer was performed. The multi instruments studies of the tri arm star polymer monitor that the polymer easily formed as a result of click chemistry.en_US
dc.language.isoengen_US
dc.publisherSPRINGER-DORDRECHTen_US
dc.relation.isversionof10.1007/s10965-020-02367-zen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectClick chemistry, Ring-opening polymerization, Hydrogen transfer polymerization, Tri arm star polymer, Terminally diazido poly(alpha-methyl beta-alanine), Terminally propargyl poly(epsilon-caprolactone), Water uptake measurementen_US
dc.titleSynthesis and characterization of poly(α-methyl β-alanine)-poly(ε-caprolactone) tri arm star polymer by hydrogen transfer polymerization, ring-opening polymerization and click chemistryen_US
dc.typearticleen_US
dc.relation.journalJOURNAL OF POLYMER RESEARCHen_US
dc.contributor.departmentOrdu Üniversitesien_US
dc.identifier.volume28en_US
dc.identifier.issue2en_US
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