Please use this identifier to cite or link to this item: http://earsiv.odu.edu.tr:8080/xmlui/handle/11489/2750
Full metadata record
DC FieldValueLanguage
dc.contributor.authorAtli, Ilknur-
dc.contributor.authorKelebekli, Latif-
dc.date.accessioned2022-08-17T07:34:47Z-
dc.date.available2022-08-17T07:34:47Z-
dc.date.issued2019-
dc.identifier.urihttp://doi.org/10.1016/j.tet.2019.130531-
dc.identifier.urihttp://earsiv.odu.edu.tr:8080/xmlui/handle/11489/2750-
dc.description.abstractThe stereoselective synthesis of methyl-substituted inositol derivative is described. Diene diacetate which is a key compound was first prepared via three steps starting from 2-methyl-p-benzoquinone. Osmium-catalyzed regio- and stereoselective dihydroxylation of diene diacetate afforded cis-diol diasetate, which then produced tetra acetate via acetylation with Ac2O-pyridine. Oxidation and acetylation of the other alkene moiety in the compound gave a hexaacetate compound stereoselectively. Finally, the acetate groups were removed by NH3 leading to formation of the desired new methyl-substituted inositol derivative having a muco-inositol-type stereochemical pattern in the six-membered ring. Spectroscopic methods were used for characterization of all synthesized compounds. (C) 2019 Elsevier Ltd. All rights reserved.en_US
dc.language.isoengen_US
dc.publisherPERGAMON-ELSEVIER SCIENCE LTD, THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLANDen_US
dc.relation.isversionof10.1016/j.tet.2019.130531en_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectInositol; Polycyclitol; Methyl-substituted muco-inositol-type pattern; Tertiary alcohol; Regioselectiveen_US
dc.titleStereoselective synthesis of a new methyl-substituted inositol derivativeen_US
dc.typearticleen_US
dc.relation.journalTETRAHEDRONen_US
dc.contributor.departmentOrdu Üniversitesien_US
Appears in Collections:Kimya

Files in This Item:
There are no files associated with this item.


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.