| dc.contributor.author |
Kelebekli, Latif |
|
| dc.date.accessioned |
2022-09-05T10:14:13Z |
|
| dc.date.available |
2022-09-05T10:14:13Z |
|
| dc.date.issued |
2013 |
|
| dc.identifier.uri |
http://doi.org/10.1080/00397911.2012.754472 |
|
| dc.identifier.uri |
http://earsiv.odu.edu.tr:8080/xmlui/handle/11489/3150 |
|
| dc.description.abstract |
Stereoselective synthesis of tricyclo[6.2.2.0(2,7)]dodecane-3,6,9,10-tetrol was developed starting from p-benzoquinone. The endo selective Diels-Alder cycloaddition of p-benzoquinone and 1,3-cyclohexadiene afforded the corresponding bicyclic diketone. The synthesis of the title compound was based on the cycloadduct by selective reduction with NaBH4, acetylation with AcCl, and hydroxylation with OsO4-NMO. [Supplementary materials are available for this article. Go to the publisher's online edition of Synthetic Communications (R) for the following free supplemental resource: Full experimental and spectral details.] |
en_US |
| dc.language.iso |
eng |
en_US |
| dc.publisher |
TAYLOR & FRANCIS INC530 WALNUT STREET, STE 850, PHILADELPHIA, PA 19106 |
en_US |
| dc.relation.isversionof |
10.1080/00397911.2012.754472 |
en_US |
| dc.rights |
info:eu-repo/semantics/openAccess |
en_US |
| dc.subject |
Stereoselective synthesis of tricyclo[6.2.2.0(2,7)]dodecane-3,6,9,10-tetrol was developed starting from p-benzoquinone. The endo selective Diels-Alder cycloaddition of p-benzoquinone and 1,3-cyclohexadiene afforded the corresponding bicyclic diketone. The synthesis of the title compound was based on the cycloadduct by selective reduction with NaBH4, acetylation with AcCl, and hydroxylation with OsO4-NMO. [Supplementary materials are available for this article. Go to the publisher's online edition of Synthetic Communications (R) for the following free supplemental resource: Full experimental and spectral details.] |
en_US |
| dc.title |
Stereoselective Synthesis of Tricyclo[6.2.2.0(2,7)]dodecane-3,6,9,10-tetrol via Selective Reduction of ,-Unsaturated 1,4-DIKetone |
en_US |
| dc.type |
article |
en_US |
| dc.relation.journal |
SYNTHETIC COMMUNICATIONS |
en_US |
| dc.contributor.department |
Ordu Üniversitesi |
en_US |
| dc.contributor.authorID |
0000-0002-6242-2589 |
en_US |
| dc.identifier.volume |
43 |
en_US |
| dc.identifier.issue |
22 |
en_US |
| dc.identifier.startpage |
2998 |
en_US |
| dc.identifier.endpage |
3009 |
en_US |