Please use this identifier to cite or link to this item: http://earsiv.odu.edu.tr:8080/xmlui/handle/11489/4274
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dc.contributor.authorCATIKER, Efkan-
dc.contributor.authorKIRLAK, Songul-
dc.contributor.authorATAKAY, Mehmet-
dc.contributor.authorSALIH, Bekir-
dc.date.accessioned2024-03-15T08:35:29Z-
dc.date.available2024-03-15T08:35:29Z-
dc.date.issued2022-
dc.identifier.citationÇATIKER, E., KIRLAK, S., ATAKAY, M., SALIH, B. (2022). Synthesis and characterization of novel poly(α-methyl β-alanine-b-lactone)s through hydrogen-transfer and ring-opening polymerization. Ovidius Univ. Ann. Chem., 33(1), 78-83. https://doi.org/10.2478/auoc-2022-0011en_US
dc.identifier.issn1583-2430-
dc.identifier.issn2286-038X-
dc.identifier.urihttp://dx.doi.org/10.2478/auoc-2022-0011-
dc.identifier.urihttps://www.webofscience.com/wos/woscc/full-record/WOS:000812694400003-
dc.identifier.urihttp://earsiv.odu.edu.tr:8080/xmlui/handle/11489/4274-
dc.descriptionWoS Categories: Chemistry, Multidisciplinaryen_US
dc.descriptionWeb of Science Index: Emerging Sources Citation Index (ESCI)en_US
dc.descriptionResearch Areas: Chemistryen_US
dc.description.abstractA series of novel poly(alpha-methyl beta-alanine-b-lactone)s were prepared by a combination of hydrogen-transfer polymerization (HTP) of methacrylamide (MAm) and anionic ring-opening polymerization (AROP) of beta-propiolactone (BPL), beta-butyrolactone (BBL), and delta-valerolactone (DVL). For this purpose, poly(alpha-methyl beta-alanine) (PmBA) having a living anionic end-group for a further extension was obtained via HTP of MAm. The anionic end-group on PmBA chains were used as initiation sites for AROP of BPL, BBL, and DVL. Fourier Transform Infrared Spectroscopy (FTIR) and Proton Nuclear Magnetic Resonance Spectroscopy (H-1-NMR) confirmed the existence of both ester and alpha-methyl beta-alanine (mBA) units in the final products. MALDI-MS analysis revealed that the poly(alpha-methyl beta-alanine-b-lactone)s with average molar masses of several thousand g.mol(-1) were obtained. DSC and TGA thermograms of each copolymer showed that the copolymers comprised the mBA and the corresponding ester units.en_US
dc.language.isoengen_US
dc.publisherOVIDIUS UNIV PRESS-CONSTANTAen_US
dc.relation.isversionof10.2478/auoc-2022-0011en_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectAB-type block copolymers, poly(amide-ester), hydrogen-transfer polymerization, ring-opening polymerizationen_US
dc.subjectPOLY-BETA-ALANINE, BLOCK-COPOLYMER, ACRYLAMIDE, OXIDE)en_US
dc.titleSynthesis and characterization of novel poly(α-methyl β-alanine-b-lactone)s through hydrogen-transfer and ring-opening polymerizationen_US
dc.typearticleen_US
dc.relation.journalOVIDIUS UNIVERSITY ANNALS OF CHEMISTRYen_US
dc.contributor.departmentOrdu Üniversitesien_US
dc.identifier.volume33en_US
dc.identifier.issue1en_US
dc.identifier.startpage78en_US
dc.identifier.endpage83en_US
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