Please use this identifier to cite or link to this item: http://earsiv.odu.edu.tr:8080/xmlui/handle/11489/4134
Title: Concise synthesis of chloro-benzoconduritols via effect of acetyl chloride (AcCl): Mattocks type reaction
Authors: Kelebekli, Latif
Ordu Üniversitesi
0000-0002-6242-2589
Keywords: Benzoconduritol-D, effect of acetyl chloride, halobenzoconduritols, Mattock type reaction, ring opening of bridged ether
CATALYZED ACYLATIVE CLEAVAGE, 2-ACYLOXYISOBUTYRYL HALIDES, CHEMOENZYMATIC SYNTHESIS, ACYCLIC ETHERS, C-H, HALOGENATION, ANALOGS, INOSITOL, NUCLEOSIDES, EFFICIENT
Issue Date: 2023
Publisher: TAYLOR & FRANCIS INC-PHILADELPHIA
Citation: Kelebekli, L. (2023). Concise synthesis of chloro-benzoconduritols via effect of acetyl chloride (AcCl): Mattocks type reaction. Synth. Commun., 53(12), 907-919. https://doi.org/10.1080/00397911.2023.2204191
Abstract: Concise and effective synthesis of novel halobenzoconduritols by the action of acetyl chloride is reported. Interesting monochloride and dichloride products are formed as a result of the reaction of benzoconduritol-D and 1,2,3,4-tetrahydro-1,4-epoxynaphthalene-2,3-diyl diacetate with acetyl chloride. We present surprising results bearing on the possible course and mechanism of the halobenzoconduritols synthesis. To the best of our knowledge, this reaction process represents the first example of the conversion of benzoconduritols to chloroesters. In terms of synthesis, the replacement of OH with halogen and its effects on neighboring groups were explained by the proposed mechanism (a Mattock-type mechanism).
Description: WoS Categories: Chemistry, Organic
Web of Science Index: Science Citation Index Expanded (SCI-EXPANDED); Index Chemicus (IC)
Research Areas: Chemistry
URI: http://dx.doi.org/10.1080/00397911.2023.2204191
https://www.webofscience.com/wos/woscc/full-record/WOS:000975818000001
http://earsiv.odu.edu.tr:8080/xmlui/handle/11489/4134
ISSN: 0039-7911
1532-2432
Appears in Collections:Kimya

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