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http://earsiv.odu.edu.tr:8080/xmlui/handle/11489/2702| Title: | Regio- and stereospecific synthesis of DL-4,5-dibromo-4,5-dideoxy-3,6-O-methyl-chiro-inositol |
| Authors: | Aksu, Kadir Kelebekli, Latif Sahin, Ertan Ordu Üniversitesi 0000-0002-6242-2589 |
| Keywords: | chiro-Inositol; Methoxy conduritol-B; Methoxy inositol; Regio- and stereospecific synthesis |
| Issue Date: | 2018 |
| Publisher: | PERGAMON-ELSEVIER SCIENCE LTD, THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND |
| Abstract: | The regio- and stereospecific synthesis of DL-4,5-dibromo-4,5-dideoxy-3,6-O-methyl-chiro-inositol is reported. Bromination of p-benzoquinone followed by reduction of the carbonyl groups with NaBH4 gave the corresponding trans-dibromodiol compound, which was reacted with sodium methoxide to produce dimethoxy conduritol-B. Regiospecific bromination of the alkene moiety furnished the desired chiro-inositol derivative. (C) 2018 Published by Elsevier Ltd. |
| URI: | http://doi.org/10.1016/j.tetlet.2018.02.050 http://earsiv.odu.edu.tr:8080/xmlui/handle/11489/2702 |
| Appears in Collections: | Kimya |
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