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http://earsiv.odu.edu.tr:8080/xmlui/handle/11489/2688| Title: | Synthesis, antimicrobial properties, and theoretical analysis of benzimidazole-2-ylidene silver(I) complexes |
| Authors: | Ayaz, Dilek Dincer, Muharrem Dusunceli, Serpil Demir Gunal, Selami Ozdemir, Ismail Ozdemir, Namik Ustun, Elvan Ordu Üniversitesi 0000-0001-6325-0216 0000-0001-8765-4039 0000-0002-0587-7261 0000-0002-4752-5176 0000-0003-3371-9874 |
| Keywords: | Antimicrobial activity; benzimidazolium salts; N-heterocyclic carbene; silver NHC complexes HETEROCYCLIC CARBENE COMPLEXES; CRYSTAL-STRUCTURES; STRUCTURAL-CHARACTERIZATION; REACTIVITY DESCRIPTORS; BIOLOGICAL-ACTIVITY; AG(I) COMPLEXES; METAL-COMPLEXES; IN-VITRO; LIGANDS; POLYMER |
| Issue Date: | 2020 |
| Publisher: | TAYLOR & FRANCIS LTD, 2-4 PARK SQUARE, MILTON PARK, ABINGDON OR14 4RN, OXON, ENGLAND |
| Abstract: | A series of symmetrical and nonsymmetricalN,N-disubstituted benzimidazolium salts were synthesized asN-heterocyclic carbene precursors. These salts were treated with Ag2O to afford their corresponding mononuclear Ag(I)-NHC complexes. These compounds were characterized by spectroscopy techniques and analyzed by DFT/TDDFT and docking methods. Also, the structures of2aand2ewere determined by single-crystal X-ray crystallography. These new Ag-NHC complexes were screened for their antibacterial activities against Gram-positive, Gram-negative bacteria, fungi, and nosocomial agents. |
| URI: | http://doi.org/10.1080/00958972.2020.1812587 http://earsiv.odu.edu.tr:8080/xmlui/handle/11489/2688 |
| Appears in Collections: | Kimya |
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