Please use this identifier to cite or link to this item: http://earsiv.odu.edu.tr:8080/xmlui/handle/11489/2674
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dc.contributor.authorKaplan, Dilek-
dc.contributor.authorKelebekli, Latif-
dc.date.accessioned2022-08-17T07:04:18Z-
dc.date.available2022-08-17T07:04:18Z-
dc.date.issued2020-
dc.identifier.urihttp://doi.org/10.1007/s13738-019-01810-3-
dc.identifier.urihttp://earsiv.odu.edu.tr:8080/xmlui/handle/11489/2674-
dc.description.abstractThe stereoselective synthesis of 2-bromo-6-chloro-5-methylcyclohex-4-ene-1,3-diyl diacetate, methyl-substituted dihaloconduritol-A is reported. Bromination of 2-methylbenzo-1,4-quinone followed by the reduction in the carbonyl groups with NaBH4 to give a dioldibromo compound. The diol was converted to diacetates by acetylation with Ac2O-pyridine. Reaction of methyl-dioldibromodiacetate with LiOH gave stereoselectively the monoepoxide compound. Controlled reaction of the epoxide with AcCl in methylene chloride furnished the desired new dihaloconduritol-A derivative which was characterized by spectroscopic methods. All the synthesized compounds were characterized by FT-IR, H-1-NMR, C-13-NMR, COSY (2D-NMR), and HRMS analyses.en_US
dc.language.isoengen_US
dc.publisherSPRINGER, ONE NEW YORK PLAZA, SUITE 4600, NEW YORK, NY, UNITED STATESen_US
dc.relation.isversionof10.1007/s13738-019-01810-3en_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectDihalogen cyclitol; Dihaloconduritol; Cyclitol; Dihaloconduritol-A derivativeen_US
dc.subjectSTEREOSPECIFIC SYNTHESIS; EPOXIDES; BROMOCONDURITOL; METABOLITESen_US
dc.titleA novel and stereoselective synthesis of 2-bromo-6-chloro-5-methylcyclohex-4-ene-1,3-diyl diacetate: conduritol-A derivativeen_US
dc.typearticleen_US
dc.relation.journalJOURNAL OF THE IRANIAN CHEMICAL SOCIETYen_US
dc.contributor.departmentOrdu Üniversitesien_US
dc.identifier.volume17en_US
dc.identifier.issue4en_US
dc.identifier.startpage803en_US
dc.identifier.endpage808en_US
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