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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Eskici, Mustafa | - |
dc.contributor.author | Karanfil, Abdullah | - |
dc.date.accessioned | 2022-08-17T06:47:34Z | - |
dc.date.available | 2022-08-17T06:47:34Z | - |
dc.date.issued | 2017 | - |
dc.identifier.uri | http://doi.org/10.1080/00397911.2017.1376334 | - |
dc.identifier.uri | https://www.tandfonline.com/doi/full/10.1080/00397911.2017.1376334 | - |
dc.identifier.uri | http://earsiv.odu.edu.tr:8080/xmlui/handle/11489/2578 | - |
dc.description.abstract | Practical and economical synthesis of synthetically valuable 3,3,3-triethoxypropyne, ketal protected phenyl and methyl substituents prop-2-ynones is described. Bromination and subsequent 18-crown-6 catalyzed elimination of triethylorthoacrylate and ketal protected terminal alkenes with methyl and phenyl substituent which are inturn readily available from triethylorthopropionate, 3-chlorobutan-2-one and propiophenone afforded multigram quantities (>10g) of corresponding functionalized terminal alkynes. Exploration of the synthetic utility of these alkynes is also demonstrated by the acetylenic substitution of the phenylalaninol derived 1,2-cyclic sulfamidate to deliver chiral alkynylated amines. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | TAYLOR & FRANCIS INC, 530 WALNUT STREET, STE 850, PHILADELPHIA, PA 19106 USA | en_US |
dc.relation.isversionof | 10.1080/00397911.2017.1376334 | en_US |
dc.rights | info:eu-repo/semantics/openAccess | en_US |
dc.subject | 1; 2-Cyclic sulfamidates; ketal; orthoester; terminal alkynes | en_US |
dc.subject | PROPIOLATE; REACTIVITY; ACETYLIDES | en_US |
dc.title | Practical synthesis of functionalized terminal alkynes, 3,3,3-triethoxypropyne and ketal protected prop-2-ynones | en_US |
dc.type | article | en_US |
dc.relation.journal | SYNTHETIC COMMUNICATIONS | en_US |
dc.contributor.department | Ordu Üniversitesi | en_US |
dc.contributor.authorID | 0000-0003-2948-4216 | en_US |
dc.identifier.volume | 47 | en_US |
dc.identifier.issue | 24 | en_US |
dc.identifier.startpage | 2342 | en_US |
dc.identifier.endpage | 2351 | en_US |
Appears in Collections: | Kimya |
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