[Mn(CO)(3)(bpy)(N-2-chlorobenzylbenzimidazole)] OTf complex as a new photoactivatable CO-releasing molecule

Please use this identifier to cite or link to this item: http://earsiv.odu.edu.tr:8080/xmlui/handle/11489/2572

Title:	[Mn(CO)(3)(bpy)(N-2-chlorobenzylbenzimidazole)] OTf complex as a new photoactivatable CO-releasing molecule
Authors:	Dusunceli, S. Demir Ozdemir, I. Ustun, E. Ordu Üniversitesi 0000-0001-6325-0216 0000-0001-8765-4039 0000-0002-0587-7261
Keywords:	CORM; carbonyl complexes; manganese GROUP-6 METAL-CARBONYLS; MANGANESE COMPLEXES; TRICARBONYL COMPLEXES; ANTIOXIDANT ACTIVITY; DFT CALCULATION; MONOXIDE; ELECTROCHEMISTRY; THERAPY; LIGANDS; DESIGN
Issue Date:	2017
Publisher:	BULGARIAN ACAD SCIENCE, CENTRAL LIBRARY 7 NOEMVRI NO 1, SOFIA, 00000, BULGARIA
Abstract:	Metal carbonyl complexes have been accepted major for storage and transportation of carbon monoxide which is an important gasotransmitter. We synthesized novel manganese(I) carbonyl complex with general formula [Mn(CO)(3)(bpy)L] OTf (bpy = 2,2'-bipyridyl, L= N-(2-chlorobenzyl) benzimidazole, OTf = SO3CF3). The complex was characterized by LC-MS, H-1 NMR, 2D-COSY NMR, C-13 NMR, IR and elemental analysis. The CO-releasing properties of the complex were investigated. The DFT/TDDFT analyses were also made by ORCA package program.
URI:	http://www.bcc.bas.bg/BCC_Volumes/Volume_49_Special_L_2017/BCC-49-L-2017.pdf https://www.researchgate.net/publication/320708575_MnCO3bpyN-2-chlorobenzylbenzimidazoleOTf_complex_as_a_new_photoactivatable_CO-releasing_molecule http://earsiv.odu.edu.tr:8080/xmlui/handle/11489/2572
Appears in Collections:	Kimya

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