Please use this identifier to cite or link to this item: http://earsiv.odu.edu.tr:8080/xmlui/handle/11489/2545
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dc.contributor.authorAsci, Gizem-
dc.contributor.authorAyvaz, Melek Col-
dc.contributor.authorCelebi, Mutlu Sonmez-
dc.contributor.authorDemir, Serpil-
dc.contributor.authorOzdemir, Ismail-
dc.contributor.authorUstun, Elvan-
dc.date.accessioned2022-08-17T06:43:03Z-
dc.date.available2022-08-17T06:43:03Z-
dc.date.issued2016-
dc.identifier.urihttp://doi.org/10.1016/j.ica.2016.05.027-
dc.identifier.urihttps://www.sciencedirect.com/science/article/pii/S0020169316302699?via%3Dihub-
dc.identifier.urihttp://earsiv.odu.edu.tr:8080/xmlui/handle/11489/2545-
dc.description.abstractMetal carbonyl complexes are prominent group organometallic compounds because of their applications in industrial and pharmaceutical chemistry. In recent years, metal carbonyl complexes have been accepted major for storage and transportation of carbon monoxide which is an important signaling molecule significantly in pathogenesis of some diseases. Thus, we designed and synthesized novel manganese (I) carbonyl complexes with general formula [Mn(CO)(3)(bpy)L]PF6 (bpy = 2,2-bipyridyl, L = N-(2-chlorobenzyl) benzimidazole, N-(2-methoxybenzyl) benzimidazole, N-(2-methylbenzyl) benzimidazole). The complex molecules were characterized by LC-MS, H-1-NMR, C-13-NMR, IR spectroscopy methods and elemental analysis. The CO-releasing properties, antioxidant activities and redox properties of these complexes were investigated. The DFT/TDDFT analyses were made by ORCA package program. (C) 2016 Elsevier B.V. All rights reserved.en_US
dc.language.isoengen_US
dc.publisherELSEVIER SCIENCE SA, PO BOX 564, 1001 LAUSANNE, SWITZERLANDen_US
dc.relation.isversionof10.1016/j.ica.2016.05.027en_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectCARBON-MONOXIDE; SPECTRAL CHARACTERIZATION; METAL-CARBONYLS; EXCITED-STATE; SCHIFF-BASE; BASIS-SETS; MOLECULES; PHOTOCHEMISTRY; INHIBITORS; CHEMISTRYen_US
dc.subjectCORMs; Manganese complexes; Antioxidant; Electrochemistry; DFT/TDDFTen_US
dc.titleStructure, CO-releasing property, electrochemistry, DFT calculation, and antioxidant activity of benzimidazole derivative substituted [Mn(CO)(3)(bpy)L]PF6 type novel manganese complexesen_US
dc.typearticleen_US
dc.relation.journalINORGANICA CHIMICA ACTAen_US
dc.contributor.departmentOrdu Üniversitesien_US
dc.contributor.authorID0000-0001-5155-5784en_US
dc.contributor.authorID0000-0001-6325-0216en_US
dc.contributor.authorID0000-0001-8765-4039en_US
dc.contributor.authorID0000-0002-0587-7261en_US
dc.contributor.authorID0000-0002-8816-6763en_US
dc.identifier.volume450en_US
dc.identifier.startpage182en_US
dc.identifier.endpage189en_US
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